Photovoltaic effects in BiFeO3

Switchable ferroelectric diode and photovoltaic effect in BiFeO3.

Unidirectional electric current flow, such as that found in a diode, is essential for modern electronics. It usually occurs at asymmetric interfaces such as p-n junctions or metal/semiconductor interfaces with Schottky barriers. We report on a diode effect associated with the direction of bulk electric polarization in BiFeO3: a ferroelectric with a small optical gap edge of approximately 2.2 el...

Enhanced photovoltaic properties in graphene/polycrystalline BiFeO3/Pt heterojunction structure

Remarkably enhanced photovoltaic effects and first-principles calculations in neodymium doped BiFeO3

Remarkably enhanced photovoltaic effects have been observed in the heterostructures of p-type A-site Nd3+-doped BiFeO3 (Bi0.9375Nd0.0625)FeO3 (or BFONd) polycrystalline ceramics and the n-type ITO thin film. The maximum power conversion is ~0.82%, which is larger than 0.015% in BiFeO3 (BFO) under blue-ultraviolet irradiation of wavelength λ = 405 nm. The current-voltage (I-V) characteristic cur...

Characterization and Photovoltaic Properties of BiFeO3 Thin Films

Bismuth ferrite (BiFeO3) thin films were prepared by a spin-coating method. Crystal structure and optical properties of the BiFeO3 films were evaluated using X-ray diffraction. The lattice constants, crystallite size, and energy gap of BiFeO3 films depended on the concentration of the BiFeO3 precursor solution. BiFeO3/CH3NH3PbI3 photovoltaic devices were fabricated to investigate photovoltaic p...

Tunable Schottky Barrier in Photovoltaic BiFeO3 Based Ferroelectric Composite Thin Films

We examine the photo-assisted polarization loop in a BiFeO3 thin film under UV light illumination. BiFeO3 thin film prepared by pulsed laser deposition method onto the BaTiO3 thin film and the polarization behavior has been measured under poling voltage. Our results show the engineered polarization due to controllable schottky barrier under inverse poling voltage. This control on schottky barri...